PI-FACE DIFFERENTIAL CONJUGATE ADDITION OF ORGANOCOPPER TO (ORTHO-SUBSTITUTED PHENYL ALPHA,BETA-UNSATURATED KETONE)CHROMIUM COMPLEXES

被引：17

作者：

UEMURA, M

ODA, H

MINAMI, T

HAYASHI, Y

机构：

[1] Faculty of Science, Osaka City University, Sumiyoshi-ku, Osaka, 558

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 35期

关键词：

(ARENE)CHROMIUM COMPLEXES; ORGANOCOPPER; 1,4-ADDITION; PI-FACE DIFFERENTIATION;

D O I：

10.1016/0040-4039(91)80040-D

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

1,4-Conjugate addition of organocopper reagents to (o-substituted phenyl alkenyl ketone)chromium complexes 3 gave the corresponding addition products 4 and 5, respectively, depending on the nature of ''organocopper'' with high stereoface differentiation. This reaction provides a method of remote stereocontrol in combination with stereoselective conversion of Cr(CO)3-complexed benzylic ketone to alkyl group.

引用

页码：4565 / 4568

页数：4

共 17 条

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