ELECTROCHEMICAL PARAMETRIZATION OF RHENIUM REDOX COUPLES

被引：178

作者：

LEVER, ABP

机构：

[1] Department of Chemistry, York University, North York (Toronto), Ontario

来源：

INORGANIC CHEMISTRY | 1991年 / 30卷 / 09期

关键词：

D O I：

10.1021/ic00009a008

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The observed rhenium potentials for Re(IV)/III, and Re(II)/I reversible couples, for mononuclear species, are analyzed in terms of the electrochemical parametrization scheme based upon the Ru(III)/II couples. Two independent sets of Re(II)/I potentials are observed, which, if extended, would cross the Re(III)/II correlation line. The possible significance of these sets is explored. The Re(IV)/II couple correlation is roughly parallel to one of the Re(II)/I correlation lines. The analysis leads to some interesting avenues for future synthetic studies.

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页码：1980 / 1985

页数：6

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