AUTOXIDATIONS OF EARLY TRANSITION METALLOCENES .1. BIS(ETA-5-PENTAMETHYLCYCLOPENTADIENYL)ZIRCONIUM(IV) DIALKYLS

被引：11

作者：

ATKINSON, JM ^{[1
]}

BRINDLEY, PB ^{[1
]}

机构：

[1] KINGSTON POLYTECH,PENRHYN RD,KINGSTON THAMES KT1 2EE,SURREY,ENGLAND

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1991年 / 411卷 / 1-2期

关键词：

D O I：

10.1016/0022-328X(91)86012-F

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Results of a study of the autoxidation of bis(eta-5-pentamethylcyclopentadienyl)zirconium alkyls of the general formulae Cp*2ZrR.X (where R = Me, CH2Ph; X = R, Cl) and that of the mixed cyclopentadienyl Cp*CpZr(CH2Ph)2 are described. Rates of initiation and oxidation are compared with those for bis(eta-5-cyclopentadienyl)zirconocenes.

引用

页码：131 / 137

页数：7

共 13 条

[1] TITANOCENE AS AN INTERMEDIATE IN REACTIONS INVOLVING MOLECULAR-HYDROGEN AND NITROGEN
BERCAW, JE
BELL, LG
BRINTZIN.HH
MARVICH, RH
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1972, 94 (04) : 1219 - &
[2] BERCAW JE, 1982, ORGANOMETALLICS, V1, P793
[3] BERCAW JE, 1978, J AM CHEM SOC, V100, P3078
[4] FREE-RADICAL SUBSTITUTION-REACTIONS ON ZIRCONIUM AND HAFNIUM ORGANOMETALLICS
BRINDLEY, PB
SCOTTON, MJ
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1981, 222 (01) : 89 - 96
[5] AUTOXIDATION OF SELECTED ALKYLS OF TITANIUM, ZIRCONIUM, MOLYBDENUM AND TUNGSTEN
BRINDLEY, PB
HODGSON, JC
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1974, 65 (01) : 57 - 64
[6] AUTOXIDATION OF ALKYL-COMPOUNDS OF ZIRCONIUM AND HAFNIUM
BRINDLEY, PB
SCOTTON, MJ
[J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1981, (02): : 419 - 421
[7] KINETICS AND RATE CONSTANTS FOR REACTIONS ASSOCIATED WITH ORGANO-BORANE AUTOXIDATIONS
BRINDLEY, PB
HODGSON, JC
SCOTTON, MJ
[J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1979, (01): : 45 - 49
[8] BRINDLEY PN, 1983, CHEM PEROXIDES, pCH23
[9] A NOVEL UNSATURATED (ALKYNE)TITANIUM(II) COMPLEX (ETA-5-C5H5)(ETA-5-C5ME5)TI(PH-C=C-PH) AND ITS COUPLING REACTION WITH CARBON-DIOXIDE
DEMERSEMAN, B
MAHE, R
DIXNEUF, PH
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1984, (21) : 1394 - 1396
[10] GRASSMAN PG, 1983, ORGANOMETALLICS, V2, P1470

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