ASYMMETRIC DIELS-ALDER CYCLOADDITION WITH CHIRAL 2-ALKYLSULFINYL-1-NITROALKENES

被引:24
作者
FUJI, K
TANAKA, K
ABE, H
ITOH, A
NODE, M
TAGA, T
MIWA, Y
SHIRO, M
机构
[1] KYOTO PHARMACEUT UNIV,YAMASHINA KU,KYOTO 607,JAPAN
[2] KYOTO UNIV,FAC PHARMACEUT SCI,SAKYO KU,KYOTO 606,JAPAN
[3] SHIONOGI & CO LTD,SHIONOGI RES LAB,FUKUSHIMA KU,OSAKA 553,JAPAN
关键词
D O I
10.1016/S0957-4166(00)82353-8
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The Diels-Alder reaction of chiral 2-alkylsulfinyl-1-nitroalkene 1 and Danishefsky's diene (2) afforded adducts 3 and 4 in good chemical yield with a high enantiomeric excess, while diastereomeric nitroalkene 7 gave 8 and 9, enantiomeric to 3 and 4, respectively.
引用
收藏
页码:179 / 182
页数:4
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