SYNTHESIS OF ALLENYLKETENIMINES VIA TITANOCENE VINYLIDENE COMPLEXES

被引：22

作者：

DENNEHY, RD ^{[1
]}

WHITBY, RJ ^{[1
]}

机构：

[1] UNIV SOUTHAMPTON,DEPT CHEM,SOUTHAMPTON SO9 5NH,HANTS,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 01期

关键词：

D O I：

10.1039/c39920000035

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The intermolecular addition of in situ generated titanocene vinylidene complexes to alkynes gives titanacyclobutenes which undergo an insertion-rearrangement with tert-butyl isocyanide to afford allenylketenimines in high yield.

引用

页码：35 / 36

页数：2

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