An X-Ray Study of the Structure of Liquid Benzene, Cyclohexane and Their Mixtures

被引:21
作者
Ward, Herbert K.
机构
关键词
D O I
10.1063/1.1749444
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Carefully purified benzene and cyclohexane exhibit x-ray diffraction peaks corresponding to preferred spacings of 4.68A and 5.09A, respectively, which are interpreted as the effective thicknesses of the respective rings. Mixtures of these two hydrocarbons give rise to two independent diffraction peaks indicating emulsion-type solutions, in which the disperse phase is too small to show even a Tyndall effect.
引用
收藏
页码:153 / 159
页数:7
相关论文
共 46 条
  • [1] BANERJEE K, 1929, INDIAN J PHYS, V3, P399
  • [2] Brucker C., 1928, PHYS Z, V29, P373
  • [3] Davey W. P., 1933, T AM SOC STEEL TREAT
  • [4] Debye P., 1916, NACHRICHTEN GESELLSC, P1
  • [5] DUBRIDGE A, 1931, PHYS REV, V37, P392
  • [6] X-ray diffraction patterns from crystalline liquid benzene
    Eastman, ED
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1924, 46 : 917 - 923
  • [7] GOOD W, 1930, HELV PHYS ACTA, V3, P205
  • [8] Good W., 1930, HELV PHYS ACTA, V3, P305
  • [9] Heil, 1933, PHYS REV, V43, P1
  • [10] Hewlett C. W., 1922, PHYS REV, V22, P688