HYDROPEROXIDES AS PSEUDOHALIDES - OXIDATION, OXIDATIVE ALKYLATION, ACYLATION AND ARYLATION OF ACRYLONITRILE

被引:17
作者
ARANEO, S [1 ]
FONTANA, F [1 ]
MINISCI, F [1 ]
RECUPERO, F [1 ]
SERRI, A [1 ]
机构
[1] POLITECN MILAN,DIPARTIMENTO CHIM,I-20131 MILAN,ITALY
关键词
D O I
10.1039/c39950001399
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
New general syntheses, based on free-radical oxidative alkylation, acylation and arylation of acrylonitrile, in the presence of Bu(t)O(2)H, are reported; the concept of the peroxy group as a pseudohalide is suggested to explain these new reactions.
引用
收藏
页码:1399 / 1400
页数:2
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