OPTICAL ROTATORY DISPERSION AND CIRCULAR DICHROISM .58. CHEMISTRY OF SANTONENE .2. AUTOXIDATION PRODUCTS AND OTHER DERIVATIVES OF SANTONENE

被引:11
作者
BARTLETT, L
SCOPES, PM
MCMURRY, TBH
MOLLAN, RC
机构
[1] Westfield College, Hampstead
[2] University Chemical Laboratory, Trinity College
来源
JOURNAL OF THE CHEMICAL SOCIETY C-ORGANIC | 1969年 / 07期
关键词
D O I
10.1039/j39690001088
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The o.r.d. and c.d. have been measured for a large number of derivatives of santonene [6-hydroxy-3-oxoeudesma-1,5,7 (11)-trien-13-oic acid 13 → 6 lactone] and have been used to assign the sterochemistry of many compounds. The chromophores studied include αβ-unsaturated lactones and more extended conjugated systems, αβ-unsaturated ketones, cross-conjugated ketones, and combinations of these types.
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页码:1088 / &
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