BIOTRANSFORMATION OF MONOTERPENOIDS, (-)-MENTHOLS AND (+)-MENTHOLS, TERPINOLENE AND CARVOTANACETONE BY ASPERGILLUS SPECIES

被引：36

作者：

ASAKAWA, Y ^{[1
]}

TAKAHASHI, H ^{[1
]}

TOYOTA, M ^{[1
]}

NOMA, Y ^{[1
]}

机构：

[1] TOKUSHIMA BUNRI UNIV,FAC DOMEST SCI,TOKUSHIMA,JAPAN

来源：

PHYTOCHEMISTRY | 1991年 / 30卷 / 12期

关键词：

ASPERGILLUS-AWAMORI; A-CELLULOSAE; A-FUMIGATUS; ASPERGILLUS-NIGER; A-SOJAE; A-TERREUS; A-USAMI; ASPERGILLACEAE; BIOTRANSFORMATION; (-)-MENTHOLS AND (+)-MENTHOLS; TERPINOLENE; (-)-CARVOTANACETONE; MOSQUITO REPELLENT;

D O I：

10.1016/0031-9422(91)83449-U

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

Four monoterpenoids. (-)- and (+)-menthols, terpinolene and carvotanacetone were biotransformed by Aspergillus niger and several related species. Aspergillus niger converted (-)-menthol to 1-, 2-, 6-, 7-, and 9-hydroxymenthols and the mosquito repellent-active 8-hydroxymenthol. On the other hand, (+)-menthol was smoothly biotransformed by A. niger to give 7-hydroxymenthol. Aspergillus cellulosae biotransformed (-)-menthol specifically to 4-hydroxymenthol. Terpinolene and (-)-carvotanacetone were converted by A. niger to two alpha,beta-unsaturated ketones, a fenchane-type compound and diastereoisomeric p-menthane-2,9-diols and 8-hydroxycarvomenthol, respectively.

引用

页码：3981 / 3987

页数：7

共 15 条

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