HETEROPOLYANIONS DOPED POLYACETYLENE - PREPARATION, SPECTROSCOPIC AND CATALYTIC PROPERTIES

被引：10

作者：

KULSZEWICZBAJER, I

ZAGORSKA, M

POZNICZEK, J

BIELANSKI, A

KRUCZALA, K

DYREK, K

PRON, A

机构：

[1] POLISH ACAD SCI,INST CATALYSIS & SURFACE CHEM,PL-30239 KRAKOW,POLAND

[2] JAGIELLONIAN UNIV,FAC CHEM,PL-30060 KRAKOW,POLAND

[3] STANISLAW STASZIC UNIV MIN & MET,DEPT MAT SCI & CERAM,PL-30059 KRAKOW,POLAND

来源：

SYNTHETIC METALS | 1991年 / 41卷 / 1-2期

关键词：

D O I：

10.1016/0379-6779(91)90991-D

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Phosphomolybdic anion doped polyacetylene can act as an extremely efficient catalyst for ethyl alcohol conversion giving acetaldehyde, ethylene and diethyl ether as the reaction products. The new catalyst exhibits 43 fold increase in redox activity and 10 fold increase in acid-base activity as compared to unsupported H3PMO12O40 studied in the same experimental conditions.

引用

页码：39 / 42

页数：4

共 10 条

[1] MODIFICATION OF POLYANILINE FILMS WITH HETEROPOLYANIONS - ELECTROCATALYTIC REDUCTION OF OXYGEN AND PROTONS
BIDAN, G
GENIES, EM
LAPKOWSKI, M
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1988, (08) : 533 - 535
[2] POLYPYRROLE AND POLY(N-METHYLPYRROLE) FILMS DOPED WITH KEGGIN-TYPE HETEROPOLYANIONS - PREPARATION AND PROPERTIES
BIDAN, G
GENIES, EM
LAPKOWSKI, M
[J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1988, 251 (02) : 297 - 306
[3] CATALYTIC REACTIONS OF ETHANOL ON H3+XPMO12-XVXO40 CATALYSTS
BIELANSKI, A
POZNICZEK, J
MALECKA, A
[J]. REACTION KINETICS AND CATALYSIS LETTERS, 1990, 41 (01): : 127 - 134
[4] FRICKE R, 1986, J CHEM SOC F1, P82
[5] X-RAY PHOTO-ELECTRON SPECTROSCOPIC STUDY OF HIGHLY CONDUCTIVE BROMINE-DOPED POLYACETYLENE
IKEMOTO, I
CAO, Y
YAMADA, M
KURODA, H
HARADA, I
SHIRAKAWA, H
IKEDA, S
[J]. BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1982, 55 (03) : 721 - 725
[6] THERMAL CIS-TRANS ISOMERIZATION AND DECOMPOSITION OF POLYACETYLENE
ITO, T
SHIRAKAWA, H
IKEDA, S
[J]. JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1975, 13 (08) : 1943 - 1950
[7] KEITA B, 1988, J ELECTROANAL CHEM, V255, P303
[8] ELECTRICAL TRANSPORT-PROPERTIES OF POLYACETYLENE TETRACHLOROFERRATE - [CH(FECL4)Y]X
PRZYBYLSKI, M
BULKA, BR
KULSZEWICZ, I
PRON, A
[J]. SOLID STATE COMMUNICATIONS, 1983, 48 (10) : 893 - 896
[9] Wagner C. D., 1989, NIST XRAY PHOTOELECT
[10] MODIFICATION OF POLYACETYLENE AND POLYALKYLTHIOPHENE BY DOPING WITH HETEROPOLYANIONS
ZAGORSKA, M
KULSZEWICZBAJER, I
LUKOMSKAGODZISZ, E
PRON, A
GLOWACKI, I
ULANSKI, J
LEFRANT, S
[J]. SYNTHETIC METALS, 1990, 37 (1-3) : 99 - 106

← 1 →