STRUCTURE OF A DINUCLEAR NICKEL COMPOUND, NI2(PPH3)2(SC3H6S)2

被引：8

作者：

CAO, R ^{[1
]}

HUANG, ZY ^{[1
]}

LEI, XJ ^{[1
]}

KANG, BS ^{[1
]}

HONG, MC ^{[1
]}

LIU, HQ ^{[1
]}

机构：

[1] CHINESE ACAD SCI,FUJIAN INST RES STRUCT MATTER,FUZHOU 350002,PEOPLES R CHINA

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1992年 / 48卷

关键词：

D O I：

10.1107/S0108270192000647

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Bis(1,2-propanedithiolato-1:2kappa2S',2kappaS2)bis-(triphenylphosphine)dinickel, [Ni2(C3H6S2)2-{(C6H5)3P}2], M(r) = 854.43, monoclinic, C2/c, a = 26.499 (13), b = 9.037 (6), c = 17.419 (7) angstrom, beta = 107.33 (3)-degrees, V = 3982.1 angstrom3, Z = 4, D(x) = 1.43 g cm-3, lambda(Mo Kalpha) = 0.71069 angstrom, mu = 12.6 cm-1, F(000) = 1776, T = 296 K, R = 0.053 and wR = 0.059 for 2575 reflections with I > 3sigma(I). The complex is a dimer, where each Ni atom is four-coordinated by one P and three S atoms with square-planar geometry. The average Ni-S and Ni-P bond lengths are 2.190 and 2.193 angstrom, respectively.

引用

页码：1654 / 1655

页数：2

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