THE REMARKABLE EFFECT OF METHANOL ON SULFIDE PHOTOOXIDATIONS - EVIDENCE FOR ITS DUAL REACTIVITY

被引：15

作者：

CLENNAN, EL

YANG, K

机构：

[1] Department of Chemistry University of Wyoming, Laramie

来源：

TETRAHEDRON LETTERS | 1993年 / 34卷 / 11期

关键词：

D O I：

10.1016/S0040-4039(00)60755-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The addition of small amounts of methanol to photooxidation mixtures of sulfides dramatically enhances sulfone in preference to sulfoxide formation. High concentrations of methanol on the other hand have the opposite effect of promoting sulfoxide in preference to sulfone formation.

引用

页码：1697 / 1700

页数：4

共 8 条

[1] REMOTE PARTICIPATION DURING PHOTOOXIDATION AT SULFUR - EVIDENCE FOR SULFURANE INTERMEDIATES
CLENNAN, EL
YANG, K
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1992, 57 (16) : 4477 - 4487
[2] KINETIC IMPLICATIONS OF REMOTE PARTICIPATION DURING PHOTOOXIDATION AT SULFUR
CLENNAN, EL
YANG, K
CHEN, XN
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1991, 56 (18) : 5251 - 5252
[3] O-17 ISOTOPIC TRACER EVIDENCE FOR THE FORMATION OF A SULFURANE INTERMEDIATE DURING SULFIDE PHOTOOXIDATION
CLENNAN, EL
YANG, K
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (10) : 4044 - 4046
[4] CHEMISTRY OF SINGLET OXYGEN .14. REACTIVE INTERMEDIATE IN SULFIDE PHOTOOXIDATION
FOOTE, CS
PETERS, JW
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1971, 93 (15) : 3795 - &
[5] CHEMISTRY OF SINGLET OXYGEN .35. NATURE OF INTERMEDIATES IN THE PHOTO-OXYGENATION OF SULFIDES
GU, CL
FOOTE, CS
KACHER, ML
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1981, 103 (19) : 5949 - 5951
[6] CHEMISTRY OF SINGLET OXYGEN .38. TEMPERATURE EFFECT ON THE PHOTO-OXIDATION OF SULFIDES
GU, CL
FOOTE, CS
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1982, 104 (22) : 6060 - 6063
[7] CHEMISTRY OF SINGLET OXYGEN .45. MECHANISM OF THE PHOTO-OXIDATION OF SULFIDES
LIANG, JJ
GU, CL
KACHER, ML
FOOTE, CS
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1983, 105 (14) : 4717 - 4721
[8] PERSULFOXIDE AND THIADIOXIRANE INTERMEDIATES IN THE REACTION OF SULFIDES AND SINGLET OXYGEN
WATANABE, Y
KURIKI, N
ISHIGURO, K
SAWAKI, Y
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (07) : 2677 - 2682

← 1 →