EQUILIBRIUM BETWEEN (ETA-1-PHOSPHAALLYL)TUNGSTEN AND (ETA-3-PHOSPHAALLYL)TUNGSTEN COMPLEXES

被引：25

作者：

MERCIER, F ^{[1
]}

MATHEY, F ^{[1
]}

机构：

[1] ECOLE POLYTECH,DEPT CHIM PHYS,CHIM PHOSPHORE & MET TRANSIT LAB,F-91128 PALAISEAU,FRANCE

来源：

ORGANOMETALLICS | 1990年 / 9卷 / 03期

关键词：

D O I：

10.1021/om00117a052

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of supermesitylvinylhalophosphine (supermesityl = 2,4,6-tri-tert-butylphenyl) with (cyclopentadienyl)tricarbonyltungsten hydride in the presence of Et3N and UV radiation yields [η1-supermesitylvinylphosphido](cyclopentadienyl)dicarbonyltungsten with a P=W double bond. This η1-complex isomerizes upon heating to give the corresponding η3-phosphaallyltungsten complex. The latter is converted back to the η1-complex upon irradiation with sunlight in CH2Cl2. © 1990, American Chemical Society. All rights reserved.

引用

页码：863 / 864

页数：2

共 12 条

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