FUSED BICYCLIC SYSTEMS THROUGH A NI-MEDIATED INTERMOLECULAR CYCLOPENTENONE ANNULATION

被引：19

作者：

CAMPS, F ^{[1
]}

LLEBARIA, A ^{[1
]}

MORETO, JM ^{[1
]}

PAGES, L ^{[1
]}

机构：

[1] CSIC,CID,DEPT QUIM ORGAN BIOL,J GIRONA 18-26,E-08034 BARCELONA,SPAIN

来源：

TETRAHEDRON LETTERS | 1992年 / 33卷 / 01期

关键词：

FUSED CYCLOPENTENONES; CARBONYLATION; NICKEL; ACETYLENES; 3-HALOCYCLOALKENES;

D O I：

10.1016/S0040-4039(00)77686-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The extension of the Ni(CO)4 promoted carbonylative cycloaddition of acetylenes and allyl halides to the 5-8 membered 3-halocycloolefins leads efficiently to the formation of the corresponding 4-5 fused 2-cyclopentenones with high regio and stereoselectivities.

引用

页码：109 / 112

页数：4

共 18 条

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