COOLIGOMERIZATION OF PHOSPHAALKYNES AND ALKYNES IN THE COORDINATION SPHERE OF RHODIUM COMPLEXES

被引:32
作者
BINGER, P
HAAS, J
HERRMANN, AT
LANGHAUSER, F
KRUGER, C
机构
[1] Max-Planck-Institut Für Kohlenforschung, Mulheim, D-4330
来源
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1991年 / 30卷 / 03期
关键词
D O I
10.1002/anie.199103101
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The 1-phospha-2-rhodacyclobutene 2 is formed upon reaction of the vinylidene complex 1 with tert-butylphosphaacetylene and subsequent ligand substitution. In the crystal, 2 can be described as a slightly distorted tetragonal bipyramid with a free coordination site.
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页码:310 / 312
页数:3
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