STEREOCHEMISTRY AND MECHANISM OF THE ASYMMETRIC HYDROGENATION OF UNSATURATED CARBOXYLIC-ACIDS CATALYZED BY BINAP RUTHENIUM(II) DICARBOXYLATE COMPLEXES

被引：100

作者：

OHTA, T

TAKAYA, H

NOYORI, R

机构：

[1] KYOTO UNIV,FAC ENGN,DEPT IND CHEM,KYOTO 606,JAPAN

[2] NAGOYA UNIV,DEPT CHEM,CHIKUSA KU,NAGOYA,AICHI 464,JAPAN

来源：

TETRAHEDRON LETTERS | 1990年 / 31卷 / 49期

关键词：

D O I：

10.1016/S0040-4039(00)97276-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The stereochemical course and pattern of deuterium incorporation of the hydrogenation of unsaturated carboxylic acids catalyzed by Ru(OCOCH3)2(binap) indicate operation of a mechanism involving metal monohydride complexes. © 1990.

引用

页码：7189 / 7192

页数：4

共 20 条

[1] DIHYDROGEN COMPLEXES OF METALLOPORPHYRINS - CHARACTERIZATION AND HYDROGEN-TRANSFER REACTIVITY
COLLMAN, JP
WAGENKNECHT, PS
HEMBRE, RT
LEWIS, NS
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (03) : 1294 - 1295
[2] STEREOCHEMISTRY OF FORMATION AND REACTIONS OF CARBONYLDICHLORO-(THREO-ALPHA-BETA-DIDEUTERIOPHENETHYL)BIS(TRIPHENYLPHOSPHINE)-RHODIUM AND CARBONYLDICHLORO-(THREO-ALPHA-BETA-DIDEUTERIOPHENETHYL)BIS(TRIPHENYLPHOSPHINE-IRIDIUM COMPLEXES
DUNHAM, NA
BAIRD, MC
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1975, (09): : 774 - 779
[3] HOMOGENEOUS HYDROGENATION AND HYDROFORMYLATION USING RUTHENIUM COMPLEXES
EVANS, D
OSBORN, JA
JARDINE, FH
WILKINSON, G
[J]. NATURE, 1965, 208 (5016) : 1203 - +
[4] HOMOGENEOUS CATALYSIS OF HYDROGENATION OF OLEFINIC COMPOUNDS BY RUTHENIUM (2) CHLORIDE
HALPERN, J
HARROD, JF
JAMES, BR
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1966, 88 (22) : 5150 - &
[5] HALPERN J, 1985, ASYMMETRIC SYNTHESIS, V5, pCH2
[6] ORGANORUTHENIUM(II) COMPLEXES FORMED BY INSERTION REACTIONS OF SOME VINYL COMPOUNDS AND CONJUGATED DIENES INTO A HYDRIDO RUTHENIUM BOND
HIRAKI, K
OCHI, N
SASADA, Y
HAYASHIDA, H
FUCHITA, Y
YAMANAKA, S
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1985, (05): : 873 - 877
[7] James B. R., 1973, HOMOGENEOUS HYDROGEN
[8] STOICHIOMETRIC HYDROGENATION OF OLEFINS USING HRUCL(PPH3)3 AND FORMATION OF AN ORTHO-METALLATED RUTHENIUM(II) COMPLEX
JAMES, BR
MARKHAM, LD
WANG, DKW
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1974, (11) : 439 - 440
[9] ASYMMETRIC HYDROGENATION OF PROCHIRAL ALKENES CATALYZED BY RUTHENIUM COMPLEXES OF (R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL
KAWANO, H
IKARIYA, T
ISHII, Y
SABURI, M
YOSHIKAWA, S
UCHIDA, Y
KUMOBAYASHI, H
[J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1989, (09): : 1571 - 1575
[10] PARA-HYDROGEN INDUCED POLARIZATION IN HYDROGENATION REACTIONS CATALYZED BY RUTHENIUM PHOSPHINE COMPLEXES
KIRSS, RU
EISENSCHMID, TC
EISENBERG, R
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (25) : 8564 - 8566

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