A HIGHLY STEREOSELECTIVE OPTICAL SWITCHING PROCESS-BASED ON DONOR-ACCEPTOR-SUBSTITUTED DISSYMMETRIC ALKENES

被引：92

作者：

JAGER, WF ^{[1
]}

DEJONG, JC ^{[1
]}

DELANGE, B ^{[1
]}

HUCK, NPM ^{[1
]}

MEETSMA, A ^{[1
]}

FERINGA, BL ^{[1
]}

机构：

[1] UNIV GRONINGEN, GRONINGEN CTR CATALYSIS & SYNTHESIS, DEPT ORGAN & MOLEC INORGAN CHEM, 9747 AG GRONINGEN, NETHERLANDS

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1995年 / 34卷 / 03期

关键词：

HELICES; MOLECULAR SWITCHES; OPTICAL DATA STORAGE; THIOXANTHENES;

D O I：

10.1002/anie.199503481

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reversible photoisomerization of the helical thioxanthenes 1 and 2 leads to photostationary states with large diastereomeric excesses. These compounds are promising starting materials for optical data storage devices. (Figure Presented.) Copyright © 1995 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：348 / 350

页数：3

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