LOW BARRIER ISOMERIZATION PROCESSES IN RADICAL CATIONS

被引：11

作者：

GEBICKI, J

机构：

[1] Institute of Applied Radiation Chemistry, Technical University

来源：

PURE AND APPLIED CHEMISTRY | 1995年 / 67卷 / 01期

关键词：

D O I：

10.1351/pac199567010055

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Methods of generation and characterization of radical cations in low temperature matrices are briefly presented. Advantages of steady-state and pulse radiolysis in the application to studies of low barrier isomerization processes in radical cations are described. Unimolecular radical cation transformations such as valence isomerization, conformational rotamerism and enolization studied by low temperature pulse radiolysis are reviewed.

引用

页码：55 / 62

页数：8

共 76 条

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