PHOTOLYSIS OF CONDENSED ALLYL CHLORIDE

被引：12

作者：

PHILLIPS, RW

VOLMAN, DH

机构：

[1] Department of Chemistry, University of California, Davis

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1969年 / 91卷 / 13期

关键词：

D O I：

10.1021/ja01041a003

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The photolysis at 254 nm of liquid allyl chloride at 27° and of solid allyl chloride at 77°K has been studied by microphotochemistry. By the use of aqueous acetone as an actinometer, quantum yields for 18 products containing six or fewer carbon atoms were determined. The primary process proposed is cleavage of the carbon-chlorine bond to give allyl radical. Mechanisms for the formation of the products are given. © 1969, American Chemical Society. All rights reserved.

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页码：3418 / &

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