MANGANESE(II) COMPLEXES INVOLVING NEUTRAL LINEAR POTENTIALLY PENTADENTATE SCHIFF-BASE LIGANDS

被引:12
作者
COLEMAN, WM
TAYLOR, LT
机构
[1] VIRGINIA POLYTECH INST & STATE UNIV,DEPT CHEM,BLACKSBURG,VA 24061
[2] USN,BIOSCI LAB,OAKLAND,CA 94625
来源
JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY | 1979年 / 41卷 / 01期
基金
美国国家卫生研究院;
关键词
D O I
10.1016/0022-1902(79)80401-7
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Manganese(II) complexes incorporating neutral linear potentially pentadentate (N5) ligands have been synthesized and characterized. Magnetic susceptibility, molar conductance, ESR spectra and infrared spectra suggest that the manganese ion is in a high spin pseudo-octahedral coordination environment. The non-reactivity of these complexes with O2 and NO is discussed and compared with previous studies involving other ligand systems. © 1979.
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页码:95 / 98
页数:4
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