SYNTHESIS OF METALLACYCLOPENTENONES BY INSERTION OF RHODIUM INTO CYCLOBUTENONES

被引：61

作者：

HUFFMAN, MA

LIEBESKIND, LS

PENNINGTON, WT

机构：

[1] EMORY UNIV,DEPT CHEM,ATLANTA,GA 30322

[2] CLEMSON UNIV,DEPT CHEM,CLEMSON,SC 29634

来源：

ORGANOMETALLICS | 1990年 / 9卷 / 08期

关键词：

D O I：

10.1021/om00158a009

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Cyclobutenones react with CIRh(PPh3)3 to give 5-rhoda-2-cyclopenten-1-ones (η2-vinylketenes). Ligand exchange gave [inline formula omitted], which was characterized by X-ray crystallography. Benzocyclobutenones react with CIRh(PPh3)3 to give mixtures of two regioisomeric rhodaindanones. © 1990, American Chemical Society. All rights reserved.

引用

页码：2194 / 2196

页数：3

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