DEVIATIONS FROM RAOULTS LAW IN H2O+D2O LIQUID-MIXTURES

被引：11

作者：

PHUTELA, RC

FENBY, DV

机构：

[1] Department of Chemistry, University of Otago, Dunedin

来源：

AUSTRALIAN JOURNAL OF CHEMISTRY | 1979年 / 32卷 / 01期

关键词：

D O I：

10.1071/CH9790197

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Deviations from Raoult's law in H2O + D2O liquid mixtures are calculated from vapour pressure isotope effects for HDO and D2O by assuming that the equilibrium H2O + HDO + D2O liquid mixtures are ideal solutions. The results are in good agreement with those obtained experimentally from liquid-mixture vapour pressure and boiling point measurements. © 1979 Australian Journal of Chemistry, All rights reserved.

引用

页码：197 / 200

页数：4

共 14 条

[1] VAPOR PRESSURE STUDIES INVOLVING SOLUTIONS IN LIGHT AND HEAVY WATERS .2. THE VAPOR PRESSURE OF HEAVY WATER AND THE SEPARATION FACTOR OF THE MIXED WATERS [J].