STRUCTURE OF SODIUM TETRAHYDROXYBORATE

被引：22

作者：

CSETENYI, LJ ^{[1
]}

GLASSER, FP ^{[1
]}

HOWIE, RA ^{[1
]}

机构：

[1] UNIV ABERDEEN,DEPT CHEM,MESTON WALK,ABERDEEN AB9 2UE,SCOTLAND

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1993年 / 49卷

关键词：

D O I：

10.1107/S0108270193000058

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

NaB(OH)4, M(r) = 101.83, monoclinic, P2(1)/a, a = 5.886 (3), b = 10.566 (6), c = 6.146 (3) angstrom, beta = 111.60(4)degrees, V = 355.4(3) angstrom3, Z = 4, D(x) = 1.903 Mg m-3, lambda(Mo Kalpha) = 0.71069 angstrom, mu = 0.27 mm-1, F(000) = 208, room temperature, R = 0.030 for 882 observed reflections with I > 3sigma(I). The structure consists of six-coordinate Na+ in cavities in a hydrogen-bonded framework of BO4 tetrahedra. Only three of the four H atoms of the anions are involved in O-H...O bonding.

引用

页码：1039 / 1041

页数：3

共 6 条

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SHELDRICK GM, 1976, SHELX PROGRAM CRYSTA

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