INSERTION OF A TRANSITION-METAL FRAGMENT INTO A HEPTAANTIMONIDE(3-) ANION - SYNTHESIS AND STRUCTURE OF [SB7MO(CO)(3)](3-)

被引:35
作者
BOLLE, U
TREMEL, W
机构
[1] UNIV MAINZ,INST ANORGAN CHEM & ANALYT CHEM,D-55128 MAINZ,GERMANY
[2] UNIV MUNSTER,INST ANORGAN CHEM,D-48149 MUNSTER,GERMANY
关键词
D O I
10.1039/c39940000217
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Reaction of Na2Sb7 with Mo(bipy)(CO)(4) (bipy = bipyridyl) and 2,2,2-crypt(4,7,13, 16,21,24-hexaoxa-1,10-diazobicyclo[8.8.8]hexacosane) in ethylenediamine results in the formation of [Na(2,2,2-crypt)](3) [Sb7Mo(CO)(3)], whose structure has been determined crystallographically.
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页码:217 / 219
页数:3
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