INSERTION OF A TRANSITION-METAL FRAGMENT INTO A HEPTAANTIMONIDE(3-) ANION - SYNTHESIS AND STRUCTURE OF [SB7MO(CO)(3)](3-)

被引：35

作者：

BOLLE, U

TREMEL, W

机构：

[1] UNIV MAINZ,INST ANORGAN CHEM & ANALYT CHEM,D-55128 MAINZ,GERMANY

[2] UNIV MUNSTER,INST ANORGAN CHEM,D-48149 MUNSTER,GERMANY

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 02期

关键词：

D O I：

10.1039/c39940000217

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of Na2Sb7 with Mo(bipy)(CO)(4) (bipy = bipyridyl) and 2,2,2-crypt(4,7,13, 16,21,24-hexaoxa-1,10-diazobicyclo[8.8.8]hexacosane) in ethylenediamine results in the formation of [Na(2,2,2-crypt)](3) [Sb7Mo(CO)(3)], whose structure has been determined crystallographically.

引用

页码：217 / 219

页数：3

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