ABSORPTION-SPECTRA OF NOBLE-METAL ATOMS ISOLATED IN MOLECULAR MATRICES

被引：16

作者：

ABE, H

SCHULZE, W

KOLB, DM

机构：

[1] Fritz-Haber-Institut der Max-Planck-Gesellschaft

来源：

CHEMICAL PHYSICS LETTERS | 1979年 / 60卷 / 02期

关键词：

D O I：

10.1016/0009-2614(79)80016-0

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Absorption spectra for Cu, Ag and Au atoms isolated in H2, D2, N2 and CH4 matrices are shown and the matrix influence on these spectra is evaluated. Unlike the inert gases, these matrices cause an unusually large crystal field splitting of the metal atom nP 3 2 level. Distinct differences in the spectra for isolation in H2 and D2 are found and discussed. © 1979.

引用

页码：208 / 211

页数：4

共 13 条

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[10] ANALYSIS OF MATRIX INDUCED CHANGES IN SPECTRA OF ISOLATED METAL ATOMS
KOLB, DM
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SCHULZE, W
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[J]. BERICHTE DER BUNSEN-GESELLSCHAFT-PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 1978, 82 (01): : 33 - 35

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