SYNTHESIS OF NOVEL DONOR-ACCEPTOR MANGANESE(I) COMPLEXES OF FERROCENYLACETYLENE - CRYSTAL-STRUCTURE OF [(C-5H-5)FE(C-5H-4) C-EQUIVALENT-TO-CMN(CO)(3)(PH2PCH(ME)CH2PPH2)] WHICH HAS POTENTIAL FOR 2ND-ORDER NONLINEAR OPTICS

被引：39

作者：

COLBERT, MCB

EDWARDS, AJ

LEWIS, J

LONG, NJ

PAGE, NA

PARKER, DG

RAITHBY, PR

机构：

[1] UNIV CAMBRIDGE,DEPT CHEM,LENSFIELD RD,CAMBRIDGE CB2 1EW,ENGLAND

[2] ICI GRP,R&T AFFAIRS,MIDDLESBROUGH TS90 8JE,CLEVELAND,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1994年 / 17期

关键词：

D O I：

10.1039/dt9940002589

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Three novel manganese(I) ferrocenylacetylide complexes have been synthesised and characterised and the crystal structure of [(C5H5)Fe(C5H4)C=CMn(CO)3{Ph2PCH(Me)CH2PPh2}] has been determined, in which the incorporation of a chiral chelating phosphine leads to crystallisation in the non-centrosymmetric space group P2(1)2(1)2(1).

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页码：2589 / 2590

页数：2

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