COUPLING OF STEREOCHEMISTRY AND PROTON DONOR-ACCEPTOR PROPERTIES OF A SCHIFF-BASE - MODEL OF A LIGHT-DRIVEN PROTON PUMP

被引：81

作者：

ORLANDI, G ^{[1
]}

SCHULTEN, K ^{[1
]}

机构：

[1] MAX PLANCK INST BIOPHYS CHEM, D-3400 GOTTINGEN, FED REP GER

来源：

CHEMICAL PHYSICS LETTERS | 1979年 / 64卷 / 02期

关键词：

D O I：

10.1016/0009-2614(79)80534-5

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

On the basis of MINDO/3, MINDO/3 CI and MNDO calculations it is demonstrated that the (photo-)isomerization (single and double bond rotations) of a Schiff base polyene depends strongly on the protonation state. The results are pertinent to the ground state behaviour and the photobehaviour of retinal in bacteriorhodopsin, a protein which acts as a light-driven proton pump in Halobacterium halobium. © 1979.

引用

页码：370 / 374

页数：5

共 17 条

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