MODEL MONOOXYGENASE REACTIVITY BY BINUCLEAR 2-COORDINATE COPPER(I) COMPLEXES EXTENDS TO NEW LIGAND SYSTEMS CONTAINING NITROGEN AND SULFUR DONORS

被引:57
作者
CASELLA, L
GULLOTTI, M
BARTOSEK, M
PALLANZA, G
LAURENTI, E
机构
关键词
D O I
10.1039/c39910001235
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The oxygen insertion reaction exhibited by binuclear two-coordinate copper(I) complexes derived from bis-imine ligands extends to systems containing additional benzimidazole, tertiary amine and thioether donor groups; an inverse correlation has been found between the rate of the reaction and the basicity of the donor group.
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页码:1235 / 1237
页数:3
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