DEHALOGENATION OF AMINODIHALOGENOBORANES BY NA/K ALLOY IN THE PRESENCE OF NAPHTHALENE, BIS(TRIMETHYLSILYL)BUTADIYNE, AND 2,5-DIMETHYL-2,4-HEXADIENE

被引：8

作者：

MARINGGELE, W ^{[1
]}

KNOP, H ^{[1
]}

BROMM, D ^{[1
]}

MELLER, A ^{[1
]}

DIELKUS, S ^{[1
]}

HERBSTIRMER, R ^{[1
]}

SHELDRICK, GM ^{[1
]}

机构：

[1] UNIV GOTTINGEN,INST ANORGAN CHEM,TAMMANNSTR 4,W-3400 GOTTINGEN,GERMANY

来源：

CHEMISCHE BERICHTE-RECUEIL | 1992年 / 125卷 / 08期

关键词：

AMINOBORANES; DIBORYLETHYNE; DIBORYL OXIDE; 2,4,5-TRIBORABICYCLO[1.1.1]PENTANE; 1,3-DIBORETANE;

D O I：

10.1002/cber.19921250805

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of naphthalene with Na/K alloy and [(2,6-diisopro-pylphenyl)methylamino]difluoroborane (1) in 1,2-dimethoxyethane yields the aminodimethoxyborane 2, the bis(amino)borane 3, the diborylethyne 4, and the diboryl oxide 5. By addition of a mixture of bis(trimethylsilyl)butadiyne or 2,5-dimethyl-2,4-hexadiene with dichloro(diisopropyIdmino)borane to Na/K alloy in hexane the 2,4,5-triborabicyclo[1.1.1]pentane 7 and the diboretane 8, resp., are obtained. H-1-, B-11-, C-13-, F-19-, (Si-NMR-)-Si-29, IR, and MS data are given. For 2 - 4, 7 and 8 X-ray structure analyses are performed.

引用

页码：1807 / 1813

页数：7

共 23 条

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