SYNTHESIS AND CHARACTERIZATION OF 2 NEW ORGANIC SUPERCONDUCTORS, KAPPA-L-[BIS(ETHYLENEDISULFANYL)TETRATHIAFULVALENE]AU-2(CF3)(4)CENTER-DOT(1,1,2-TRICHLOROETHANE) AND KAPPA-H-[BIS(ETHYLENEDISULFANYL)TETRATHIAFULVALENE]AU-2(CF3)(4)CENTER-DOT(1,1,2-TRICHLOROETHANE) VIA MICROELECTROCRYSTALLIZATION

被引：35

作者：

SCHLUETER, JA

WILLIAMS, JM

GEISER, U

DUDEK, JD

SIRCHIO, SA

KELLY, ME

GREGAR, JS

KWOK, WH

FENDRICH, JA

SCHIRBER, JE

BAYLESS, WR

NAUMANN, D

ROY, T

机构：

[1] ARGONNE NATL LAB,DIV SCI MAT,ARGONNE,IL 60439

[2] SANDIA NATL LABS,ALBUQUERQUE,NM 87185

[3] UNIV COLOGNE,INST ANORGAN CHEM,D-50939 COLOGNE,GERMANY

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 13期

关键词：

D O I：

10.1039/c39950001311

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel microelectrocrystallization (MEC) procedure (ten-fold decrease in halogenated solvent-use, micromolar quantities of electron donor molecule and supporting electrolyte, and Hg free electrodes), necessitated by the very small available quantities of the novel organometallic AU(CF3)(4)- anion, has been developed to prepare two distinct phases of kappa-(ET)(2)Au(CF3)(4) .(TCE) [ET = bis(ethylenedisulfanyl)tetrathiafulvalene, TCE = 1,1,2-trichloroethane] which exhibit ambient pressure superconductivity with onset temperature of 2.1 and 10.5 K.

引用

页码：1311 / 1312

页数：2

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