KINETICS AND SPECTROSCOPY OF ELECTRONICALLY EXCITED BIO OBTAINED BY ENERGY-TRANSFER FROM METASTABLE O2 .2. SPECTROSCOPIC ANALYSIS OF THE A(2-PI-1/2)-X1(2-PI-1/2) TRANSITION

被引：7

作者：

MARTIN, F

BACIS, R

LINTON, C

VERGES, J

MAYO, I

ROSENWAKS, S

机构：

[1] CNRS,AIME COTTON LAB,F-91405 ORSAY,FRANCE

[2] BEN GURION UNIV NEGEV,DEPT PHYS,IL-84105 BEER SHEVA,ISRAEL

[3] UNIV NEW BRUNSWICK,DEPT PHYS,FREDERICTON E3B 5A3,NB,CANADA

来源：

JOURNAL OF CHEMICAL PHYSICS | 1991年 / 95卷 / 01期

关键词：

D O I：

10.1063/1.461482

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The A(2-PI-1/2)X1(2-PI-1/2) transition of BiO was studied via high resolution Fourier transform spectroscopy in the 7550-20 000 cm-1 region. BiO in the A state was obtained in a mixture of Bi vapor and O2 (1-DELTA-g, 1-SIGMA-g+). From rotational and vibrational analysis of the spectrum, equilibrium constants for both the X1 ground state and the A excited state have been calculated. The magnetic hyperfine constant of the ground state of BiO has been found to be 0.0928 (4) cm-1.

引用

页码：255 / 261

页数：7

共 15 条

[1] MAGNETIC HYPERFINE INTERACTIONS IN ELECTRONIC SPECTRA OF DIATOMIC MOLECULES .2. MAGNETIC INTERACTIONS IN HUNDS CASE (C) AND SPECTRAM OF BIO [J].

ATKINS, PW .

PROCEEDINGS OF THE ROYAL SOCIETY OF LONDON SERIES A-MATHEMATICAL AND PHYSICAL SCIENCES, 1967, 300 (1463) :487-&

[2] MAGNETIC HYPERFINE INTERACTIONS IN ELECTRONIC SPECTRA OF DIATOMIC MOLECULES .I. ROTATIONAL STRUCTURE OF ABSORPTION BANDS OF GASEOUS BIO [J].

BARROW, RF ;

GISSANE, WJM ;

RICHARDS, D .

PROCEEDINGS OF THE ROYAL SOCIETY OF LONDON SERIES A-MATHEMATICAL AND PHYSICAL SCIENCES, 1967, 300 (1463) :469-&

[3]

Connes J., 1970, Nouvelle Revue d'Optique Appliquee, V1, P3, DOI 10.1088/0029-4780/1/1/301

[4] CORRECTIONS [J].

GISSANE, WJM .

PROCEEDINGS OF THE PHYSICAL SOCIETY OF LONDON, 1965, 86 (551P) :682-&

[5]

GISSANE WJM, P PHYS SOC LOND, V85, P1048

[6]

GOSH C, 1933, Z PHYS, V86, P241

[7]

Guelachvili G., 1972, Nouvelle Revue d'Optique Appliquee, V3, P317, DOI 10.1088/0029-4780/3/6/304

[8]

Herzberg G., 1966, ELECT SPECTRA ELECT

[9]

MAYO I, 1990, J CHEM PHYS, V93, P11

[10] MOLECULAR-BEAM ELECTRIC RESONANCE STUDY OF HYPERFINE LAMBDA-DOUBLING SPECTRUM OF OH, OD, SH, AND SD [J].

MEERTS, WL ;

DYMANUS, A .

CANADIAN JOURNAL OF PHYSICS, 1975, 53 (19) :2123-2141

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