ENANTIOSELECTIVE ALPHA-HYDROGEN-ATOM ABSTRACTION FROM AN ESTER BY AN OPTICALLY-ACTIVE AMINE-BORYL RADICAL

被引：20

作者：

MOK, PLH ^{[1
]}

ROBERTS, BP ^{[1
]}

机构：

[1] UNIV LONDON UNIV COLL,DEPT CHEM,CHRISTOPHER INGOLD LABS,20 GORDON ST,LONDON WC1H 0AJ,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 03期

关键词：

D O I：

10.1039/c39910000150

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The optically active amine-boryl radical IpcBH<--NMe2CH2CH2NMe2-->BH2Ipc (Ipc = isopinocampheyl) abstracts hydrogen enantioselectively from the alpha-C-H group of methyl 2-phenylpropanoate; partial kinetic resolution of the ester has been achieved in a catalytic manner.

引用

页码：150 / 152

页数：3

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