BORIDE CLUSTER FUSION VIA AN M4-UNIT (M = CU OR AG) - MOLECULAR-STRUCTURE OF [PPN][[-RU4H(CO)12B-]2CU4(MU-CL)][CL] [PPN = (PPH3)2N]

被引：13

作者：

DRAPER, SM

HATTERSLEY, AD

HOUSECROFT, CE

RHEINGOLD, AL

机构：

[1] UNIV CAMBRIDGE,CHEM LAB,LENSFIELD RD,CAMBRIDGE CB2 1EW,ENGLAND

[2] UNIV DELAWARE,DEPT CHEM,NEWARK,DE 19716

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 18期

关键词：

D O I：

10.1039/c39920001365

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of [ppn][Ru4H(CO)12BH] with [Cu(MeCN)4][BF4] in the presence of [ppn][Cl] yields [ppn][{Ru4H(CO)12B}2-Cu4(mu-Cl)][Cl], which has been structurally characterised; the introduction of silver in place of copper yields [ppn][{Ru4H(CO)12BH}2Ag] in addition to [ppn][{Ru4H(CO)12B}2Ag4(mu-Cl)][Cl].

引用

收藏

页码：1365 / 1367

页数：3

相关论文

共 38 条

[1] A NEW TYPE OF SANDWICH COMPLEX FORMED BY AG-1 AND [PT-3(MU-2-CO)3(PIPR-3)3] [J].

ALBINATI, A ;

DAHMEN, KH ;

TOGNI, A ;

VENANZI, LM .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1985, 24 (09) :766-767

[2] REACTIONS OF [RU2(MU-1,2-(NH)2C6H4)(CO)4(PPH3)2] WITH H+, NO+ AND GROUP-11 METAL FRAGMENTS - SYNTHESES OF TRINUCLEAR RU2M RU2CU, RU2AG, RU2AU AND PENTANUCLEAR RU4AU CLUSTERS [J].

ANILLO, A ;

CABEZA, JA ;

OBESOROSETE, R ;

RIERA, V .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1990, 393 (03) :423-429

[3] STRUCTURE OF TETRAPHENYLARSONIUM BIS(MU-6-CARBIDO-2,3-4,5-DI-MU-CARBONYL-1,1,1,2,2,3,3,-4,4,5,5,6,6,6-TETRADECACARBONYL-OCTAHEDRO-HEXARUTHENIO-RU3,RU4)THALLATE(1-)(4TL-RU), [AS(C6H5)4][(RU6C(CO)16)2TL] [J].

ANSELL, GB ;

MODRICK, MA ;

BRADLEY, JS .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1984, 40 (AUG) :1315-1318

[4] THE SYNTHESIS AND X-RAY STRUCTURE-ANALYSIS OF THE DIANION [RU18(C)2(CO)42HG3]2-, THE 1ST OCTADECARUTHENIUM CLUSTER [J].

BAILEY, PJ ;

JOHNSON, BFG ;

LEWIS, J ;

MCPARTLIN, M ;

POWELL, HR .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1989, (20) :1513-1515

[5] NOVEL HIGH-NUCLEARITY HGCORU AND HGCOFE SANDWICH COMPLEXES - SYNTHESIS AND STRUCTURE OF [HG(RUCO3(MU-CO)3(CO)9)2] [J].

BRAUNSTEIN, P ;

ROSE, J ;

TIRIPICCHIO, A ;

CAMELLINI, MT .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1985, 24 (09) :767-768

[6]

BROWN SSD, 1979, INORG SYNTH, V19, P315

[7] SYNTHESIS AND CHARACTERIZATION OF TETRARUTHENABORANE CLUSTERS - MOLECULAR-STRUCTURE OF [HRU4(CO)12AU2(PPH3)2B] [J].

CHIPPERFIELD, AK ;

HOUSECROFT, CE ;

RHEINGOLD, AL .

ORGANOMETALLICS, 1990, 9 (03) :681-687

[8] SYNTHESIS AND CHARACTERIZATION OF GOLD ADDUCTS OF [M(TPPME)(P3)] [M = CO, RH, OR IR - TPPME = 1,1,1-TRIS(DIPHENYLPHOSPHINOMETHYL)ETHANE] - X-RAY CRYSTAL-STRUCTURES OF [AU(M(TPPME)(P3))2]PF6 (M = CO, RH, OR IR) [J].

DIVAIRA, M ;

STOPPIONI, P ;

PERUZZINI, M .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1990, (01) :109-113

[9] SYNTHESES OF HETEROTETRANUCLEAR METALLACARBORANES CONTAINING A PLANAR MO2CU2,W2CU2 RHOMB AND B-H-CU BRIDGES - STRUCTURE OF [MO2CU2(MU-CO)4(CO)2(MU-H)2(C2B9H10)2]2- [J].

DO, Y ;

KNOBLER, CB ;

HAWTHORNE, MF .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (06) :1853-1854

[10] MULTINUCLEAR NMR-STUDIES ON MIXED COPPER IRON CARBONYL CLUSTERS [J].

DOYLE, G ;

HEATON, BT ;

OCCHIELLO, E .

ORGANOMETALLICS, 1985, 4 (07) :1224-1225

← 1 2 3 4 →