CHIRAL SYNTHESIS OF (-)-MESEMBRANOL STARTING FROM D-GLUCOSE

被引：11

作者：

CHIDA, N

SUGIHARA, K

OGAWA, S

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 07期

关键词：

D O I：

10.1039/c39940000901

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The chiral synthesis of the Sceletium alkaloid, (-)-mesembranol 1 is described; the cyclohexane ring in 1 is prepared in an optically active form from D-glucose using Ferrier's carbocyclisation reaction and the perhydroindole skeleton is effectively constructed by an intramolecular aminomercuration reaction.

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页码：901 / 902

页数：2

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