FUNCTIONAL MONOMERS AND POLYMERS .19. COPOLYMERIZATION OF VINYL MONOMERS CONTAINING NUCLEIC-ACID BASES

被引：26

作者：

TAKEMOTO, K ^{[1
]}

AKASHI, M ^{[1
]}

INAKI, Y ^{[1
]}

机构：

[1] OSAKA UNIV,FAC ENGN,DEPT PETROCHEM,SUITA,OSAKA,JAPAN

来源：

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY | 1974年 / 12卷 / 08期

关键词：

CHEMICAL REACTIONS - Reaction Kinetics - POLYMERIZATION - Copolymerization - POLYMERS - Molecular Structure;

D O I：

10.1002/pol.1974.170120826

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Taking into account the specific base-base interaction existing between nucleic acid molecules, the authors studied the free-radical copolymerization of N- beta -methacryloyloxethyl derivative of uracil with that of adenine at 60C in various solvents. N- beta -Methacryloyloxyethyltheophylline as well as methyl methacrylate were used also as comonomers. From the data on the rates in different comonomer feed ratios and the r//1 and r//2 values obtained, copolymerizability was discussed in some detail. The results suggest that the interaction between uracil and adenine bases plays a role in the copolymerization behavior.

引用

页码：1861 / 1869

页数：9

共 16 条

[1]

AKASHI M, UNPUBLISHED DATA

[2] STUDIES IN POLYMERIZATION .6. ACRYLONITRILE - THE BEHAVIOUR OF FREE RADICALS IN HETEROGENEOUS SYSTEMS [J].