SYNTHESIS AND THERMOLYSIS OF A PHOSPHORUS(III) OXALATE - EVIDENCE FOR THE GENERATION OF AN ARYLPHOSPHINIDENE OXIDE

被引：18

作者：

COWLEY, AH

GABBAI, FP

CORBELIN, S

DECKEN, A

机构：

[1] Department of Chemistry and Biochemistry, The University of Texas at Austin, Austin

[2] Department of Chemistry, University of New Brunswick, Bag Service 45222, Fredericton, NB

来源：

INORGANIC CHEMISTRY | 1995年 / 34卷 / 24期

关键词：

D O I：

10.1021/ic00128a001

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Synthesis and Thermolysis of a Phosphorus(III) Oxalate. Evidence for the Generation of an Arylphosphimidene Oxide The phosphorus(III) oxalate pictured (1) was prepared via the reaction of Ar'PGl(2) (Ar' = 2,4,6-t-Bu(3)C(6)H(2)) with Ag2C2O4. The existence of a planar five-membered PO2C2 ring was demonstrated by X-ray crystallography. The intermediacy of the phosphinidene oxide Ar'PO in the thermolysis of 1 is discussed.

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页码：5931 / &

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