THE EFFECT OF LIGHT ABSORBENCY ON THE DECOMPOSITION OF CHLOROPHENOLS BY ULTRAVIOLET-RADIATION AND UV/H2O2 PROCESSES

被引:110
作者
SHEN, YS [1 ]
KU, Y [1 ]
LEE, KC [1 ]
机构
[1] NATL TAIWAN INST TECHNOL, DEPT CHEM ENGN, TAIPEI 10772, TAIWAN
关键词
ULTRAVIOLET IRRADIATION; UV/H2O2; PROCESS; CHLOROPHENOLS;
D O I
10.1016/0043-1354(94)00198-G
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
The effect of light absorbance on the decomposition of chlorophenols in aqueous solution by ultraviolet radiation and u.v./H2O2 oxidation was studied. The light absorbance and photolytic properties of chlorophenols and H2O2 were found to be highly dependent on the solution pH and can be adequately described with the two species distribution model. For u.v./H2O2 process, the individual contribution to the decomposition of chlorophenols by direct photolysis and free hydroxyl radical destruction was differentiated by studying the u.v. light absorbance of various chlorophenols and H2O2 species.
引用
收藏
页码:907 / 914
页数:8
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