CONTINUED DEVELOPMENT OF A KINETIC MECHANISM FOR PHOTO-CHEMICAL SMOG

被引:75
作者
FALLS, AH [1 ]
SEINFELD, JH [1 ]
机构
[1] CALTECH,DEPT CHEM ENGN,PASADENA,CA 91125
关键词
Air pollution - GASES - Analysis;
D O I
10.1021/es60148a005
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
A kinetic mechanism for photochemical smog is developed to incorporate recent new information on rate constants and mechanisms. The predictions of the mechanism are compared with smog chamber data on propylene, n-butane, and propylene/n-butane systems. Areas of uncertainty are delineated, and the influence of these uncertainties on the predictions of the mechanism is discussed.
引用
收藏
页码:1398 / 1406
页数:9
相关论文
共 38 条
  • [1] REACTIONS OF METHOXYL ETHOXYL AND T-BUTOXYL WITH NITRIC OXIDE AND NITROGEN DIOXIDE
    BAKER, G
    SHAW, R
    [J]. JOURNAL OF THE CHEMICAL SOCIETY, 1965, (DEC): : 6965 - &
  • [2] PHOTOCHEMICAL SMOG - RATE PARAMETER ESTIMATES AND COMPUTER SIMULATIONS
    BALDWIN, AC
    BARKER, JR
    GOLDEN, DM
    HENDRY, DG
    [J]. JOURNAL OF PHYSICAL CHEMISTRY, 1977, 81 (25) : 2483 - 2492
  • [3] DECOMPOSITION OF DIMETHYL PEROXIDE AND RATE CONSTANT FOR CH3O+O2-]CH2O+HO2
    BARKER, JR
    BENSON, SW
    GOLDEN, DM
    [J]. INTERNATIONAL JOURNAL OF CHEMICAL KINETICS, 1977, 9 (01) : 31 - 53
  • [4] GAS-PHASE PYROLYSIS OF ALKYL NITRITES .2. S-BUTYL NITRITE
    BATT, L
    MCCULLOCH, RD
    [J]. INTERNATIONAL JOURNAL OF CHEMICAL KINETICS, 1976, 8 (06) : 911 - 933
  • [5] BATT L, 1975, INT J CHEM KINET, V1, P441
  • [6] GAS-PHASE PYROLYSIS OF ALKYL NITRITES .1. TERT-BUTYL NITRITE
    BATT, L
    MILNE, RT
    [J]. INTERNATIONAL JOURNAL OF CHEMICAL KINETICS, 1976, 8 (01) : 59 - 84
  • [7] EVIDENCE FOR ALKOXY RADICAL ISOMERIZATION IN PHOTOOXIDATIONS OF C4-C6 ALKANES UNDER SIMULATED ATMOSPHERIC CONDITIONS
    CARTER, WPL
    DARNALL, KR
    LLOYD, AC
    WINER, AM
    PITTS, JN
    [J]. CHEMICAL PHYSICS LETTERS, 1976, 42 (01) : 22 - 27
  • [8] KINETIC STUDY OF HONO FORMATION AND DECAY REACTIONS IN GASEOUS MIXTURES OF HONO, NO, NO2, H2O, AND N2
    CHAN, WH
    NORDSTROM, RJ
    CALVERT, JG
    SHAW, JH
    [J]. ENVIRONMENTAL SCIENCE & TECHNOLOGY, 1976, 10 (07) : 674 - 682
  • [9] THERMAL-DECOMPOSITION OF PEROXYACETYLNITRATE IN PRESENCE OF NITRIC-OXIDE
    COX, RA
    ROFFEY, MJ
    [J]. ENVIRONMENTAL SCIENCE & TECHNOLOGY, 1977, 11 (09) : 900 - 906
  • [10] Cvetanovic R.J., 1976, 12 INT S FREE RAD