ACID-CATALYZED DIMERIZATION OF 10-METHYLENEANTHRONE - SYNTHESIS OF SPIRO-SUBSTITUTED BENZ[DE]ANTHRACENES

被引：14

作者：

BECKER, HD ^{[1
]}

SANCHEZ, D ^{[1
]}

机构：

[1] UNIV GOTHENBURG,S-41296 GOTHENBURG,SWEDEN

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1979年 / 44卷 / 11期

关键词：

D O I：

10.1021/jo01325a009

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The acid-catalyzed dimerization of 10-methyleneanthrone is found to give 7ʹ-hydroxy-1ʹ,2ʹ-dihydrospiro[anthra-cene-9(10H),3ʹ-[3H]benz[de]anthracen]-10-one (9a), which in solution is in equilibrium with its keto tautomer 9b. Previously proposed structures of the methyleneanthrone dimer are thus being corrected. © 1979, American Chemical Society. All rights reserved.

引用

页码：1787 / 1792

页数：6

共 16 条

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