PREPARATION AND STRUCTURE OF [CS(18-CROWN-6)[TCNCL4] - AN INFINITE SANDWICH CS+ CROWN-ETHER COMPLEX CONTAINING POLYMERIC [TCNCL4] - ANIONS

被引：16

作者：

BALDAS, J

COLMANET, SF

WILLIAMS, GA

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 14期

关键词：

D O I：

10.1039/c39910000954

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The compound [Cs(18-crown-6)] [TcNCl4] is prepared and is shown to consist of an 'infinite sandwich' Cs+ cation/crown ether configuration and two types of polymeric [TcNCl4]- anions, with distinct Tc = N distances of 1.56(3) and 1.693(5) angstrom, and Tc = N...Tc separations of 4.275(4) angstrom.

引用

页码：954 / 956

页数：3

共 16 条

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