STEREOSPECIFIC POLYMERIZATION OF PROPYLENE-OXIDE ON THERMALLY ACTIVATED SYNTHETIC HYDROTALCITE

被引：32

作者：

LAYCOCK, DE ^{[1
]}

COLLACOTT, RJ ^{[1
]}

SKELTON, DA ^{[1
]}

TCHIR, MF ^{[1
]}

机构：

[1] UNIV WATERLOO,DEPT CHEM,WATERLOO N2L 3G1,ONTARIO,CANADA

来源：

JOURNAL OF CATALYSIS | 1991年 / 130卷 / 02期

关键词：

D O I：

10.1016/0021-9517(91)90119-O

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The stereodirecting influence of a thermally activated synthetic hydrotalcite material on the polymerization of propylene oxide has been demonstrated. Racemic propylene oxide can be polymerized to yield a crystalline, isotactic polymer fraction and a liquid, atactic fraction. (S)-(-)propylene oxide, under similar conditions, yields an optically active crystalline fraction and a liquid fraction of considerably reduced optical activity. Both liquid fractions exhibit a high degree of regioirregularity in the polymer chain. © 1991.

引用

页码：354 / 358

页数：5

共 20 条

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