DOUBLE STEREODIFFERENTIATING DREIDING-SCHMIDT REACTIONS

被引：12

作者：

CSUK, R ^{[1
]}

GLANZER, BI ^{[1
]}

HU, Z ^{[1
]}

BOESE, R ^{[1
]}

机构：

[1] UNIV GESAMTHSCH ESSEN,INST ANORGAN CHEM,D-45117 ESSEN,GERMANY

来源：

TETRAHEDRON | 1994年 / 50卷 / 04期

关键词：

D O I：

10.1016/S0040-4020(01)80822-X

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Spiroanellated carbohydrate-derived alpha-methyfene-gamma-butyrolactones with an additional stereogenic centre in the beta-position of the anellated lactone ring and spiroanellated alpha-alkylidens-gamma-butyrolactones were obtained in a stereosetective manner by Dreiding-Schmidt reactions of the deoxy-uloside 1 or of 2,3-O-isopropylidene-D-erythronolaetone (2) with the corresponding (Z) alkyl-2-bromomethyl-2-alkenoates in the presence of the highly reactive zinc-silver/graphite surface compound.

引用

页码：1111 / 1124

页数：14

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