REACTION OF DIPHENYLTIN WITH ALKYL HALIDES NUCLEAR MAGNETIC RESONANCE SPECTRA OF METHYLTIN AND ETHYLTIN COMPOUNDS

被引:37
作者
SISIDO, K
MIYANISI, T
NABIKA, K
KOZIMA, S
机构
[1] Department of Industrial Chemistry, Kyôto University, Kyôto
关键词
D O I
10.1016/0022-328X(68)80050-6
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Treatment of diphenyltin, (Ph2Sn)m, with alkyl halide, RX, afforded Ph2RSnX, Ph3SnX, PhRSnX2, PhR2SnX and Ph2SnX2. The mode of formation of these compounds was studied. The NMR spectra of the mixed tetra-substituted methyl and ethyltin compounds were studied systematically. Shielding constants for chemical shifts, and empirical parameters for coupling constants of the respective substituents were determined. © 1968.
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页码:281 / &
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