METALLOPORPHYRIN CONTAINING CARBYNE-LIKE CARBIDO CARBON - 5,10,15,20-TETRAPHENYLPORPHYRINATO[BIS(MU-CARBIDOTRICARBONYLRHENIUM)]TIN(IV)

被引：30

作者：

NODA, I ^{[1
]}

KATO, S ^{[1
]}

MIZUTA, M ^{[1
]}

YASUOKA, N ^{[1
]}

KASAI, N ^{[1
]}

机构：

[1] OSAKA UNIV,FAC ENGN,DEPT APPL CHEM,SUITA,OSAKA 565,JAPAN

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1979年 / 18卷 / 01期

关键词：

D O I：

10.1002/anie.197900831

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In the μ‐carbido complex 4, obtained as shown below, the tin atom is linked to the rhenium atoms via a carbide carbon atom which bonds like a carbyne to the rhenium (TPP stands for tetraphenylporphyrin). An impression of the spatial arrangement of the complexes of type 3, which are formed at only slightly higher temperatures than 4, is provided by the adjacent formula. (Figure Presented.) (Figure Presented.) Copyright © 1979 by Verlag Chemie, GmbH, Germany

引用

页码：83 / 83

页数：1

共 6 条

[1] A RHENIUM-TO-THENIUM TRIPLE BOND [J].

BENNETT, MJ ;

COTTON, FA ;

WALTON, RA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1966, 88 (16) :3866-&

[2] PREPARATION OF A NEW SERIES OF TRINUCLEAR METALLOPHTHALOCYANINES AND METALLOPORPHYRINS [J].

KATO, S ;

NODA, I ;

MIZUTA, M ;

ITOH, Y .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1979, 18 (01) :82-83

[3]

KATO S, 1979, ANGEW CHEM, V91, P84

[4]

Pauling L., 1960, NATURE CHEM BOND

[5]

TSUTSUI M, 1975, J AM CHEM SOC, V97, P3952, DOI 10.1021/ja00847a015

[6]

YASUOKA N, 1970, B CHEM SOC JPN, V43, P1601

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