LASER RAMAN-SPECTRA OF SOME GROUP-IB METAL-CARBONYL CATIONS

被引：17

作者：

NEPPEL, A

HICKEY, JP

BUTLER, IS

机构：

[1] Department of Chemistry, Mcgill University, Montreal, Quebec, H3A 2K6

来源：

JOURNAL OF RAMAN SPECTROSCOPY | 1979年 / 8卷 / 01期

关键词：

D O I：

10.1002/jrs.1250080113

中图分类号：

O433 [光谱学];

学科分类号：

0703 ; 070302 ;

摘要：

The Raman spectra of [Ag(CO)2]+ and [Cu(CO)4]+ in fluorosulphonic acid at—50°C have been investigated in the CO stretching region. These data, together with previously reported infrared results, favour D∞h symmetry for the Ag(I) species and Td symmetry for the Cu(I) species. These structures are in accord with those predicted for the complexes using the valence shell electron pair repulsion (VSEPR) theory. Copyright © 1979 Heyden & Son Ltd.

引用

页码：57 / 59

页数：3

共 15 条

[1] Adams D.M., 1967, METAL LIGAND RELATED
[2] BARNA GG, 1972, THESIS MCGILL U
[3] CARBONYL CHEMISTRY OF GROUP IB METALS
BRUCE, MI
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1972, 44 (02) : 209 - +
[4] Cotton F.A., 1972, ADV INORGANIC CHEM
[5] STUDIES OF SOLUTION CHARACTER BY MOLECULAR SPECTROSCOPY .6. EXPERIMENTAL METHODS IN ION SITE CHARACTERIZATION - SOLVENTS WITH SIMPLE SITE CHARACTER
EDGELL, WF
BARBETTA, A
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1974, 96 (02) : 415 - 423
[6] THE INFRARED SPECTRA OF METAL CARBONYLATE IONS - BONDING CONSIDERATIONS
EDGELL, WF
HUFF, J
THOMAS, J
LEHMAN, H
ANGELL, C
ASATO, G
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1960, 82 (05) : 1254 - 1255
[7] ELECTRON-PAIR REPULSION MODEL FOR MOLECULAR GEOMETRY
GILLESPIE, RJ
[J]. JOURNAL OF CHEMICAL EDUCATION, 1970, 47 (01) : 18 - +
[8] RAMAN SPECTRA OF SULPHURIC, DEUTEROSULPHURIC, FLUOROSULPHURIC, CHLOROSULPHURIC, AND METHANESULPHONIC ACIDS AND THEIR ANIONS
GILLESPIE, RJ
ROBINSON, EA
[J]. CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1962, 40 (04): : 644 - &
[9] BONDING IN M(CO)N GROUPS (WHEREN=1,2,3 AND 4)
KETTLE, SFA
[J]. JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1966, (04): : 420 - &
[10] KUNDIG EP, 1973, J AM CHEM SOC, V95, P7234

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