NEW DATA-ANALYSIS METHOD FOR THE EVALUATION OF IONIZATION-CONSTANTS AND OTHER THERMODYNAMIC FUNCTIONS FROM THE TEMPERATURE-DEPENDENCE OF THE ELECTROMOTIVE-FORCE OF CELLS

被引：15

作者：

BUTIKOFER, HP ^{[1
]}

COVINGTON, AK ^{[1
]}

EVANS, DA ^{[1
]}

机构：

[1] UNIV NEWCASTLE UPON TYNE,DEPT STAT,NEWCASTLE TYNE NE1 7RU,TYNE & WEAR,ENGLAND

来源：

ELECTROCHIMICA ACTA | 1979年 / 24卷 / 10期

关键词：

D O I：

10.1016/0013-4686(79)85003-3

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

A multilinear regression method is presented by which the analysis of emf data for electrochemical cells as a function of electrolyte concentration and temperature is achieved in a single stage yielding thermodynamic quantities and their estimated standard errors. This procedure is considered to be an advance over the two-stage method of treating the concentration and temperature variation separately. The new method is applied to selected literature data for the evaluation of the standard potential of the silver-silver chloride electrode, the autoprotolysis constants of light and heavy waters and the second ionization constant of glycerol-2-phosphate. © 1979.

引用

页码：1071 / 1079

页数：9

共 20 条

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