THE NONRESONANT 2-PHOTON ZERO KINETIC-ENERGY PHOTOELECTRON-SPECTRUM OF CS2

被引：54

作者：

FISCHER, I

LOCHSCHMIDT, A

STROBEL, A

NIEDNERSCHATTEBURG, G

MULLERDETHLEFS, K

BONDYBEY, VE

机构：

[1] Institut für Physikalische und Theoretische Chemie der TU München, W-8046 Garching

来源：

CHEMICAL PHYSICS LETTERS | 1993年 / 202卷 / 06期

关键词：

D O I：

10.1016/0009-2614(93)90045-3

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The high-resolution zero kinetic energy photoelectron spectrum of CS2 is presented. Accurate values for the ionization potential and the spin-orbit splitting of the X+ 2PI(g) are obtained. Observation of the symmetry-forbidden excitations of the nu2 bending vibration yields accurate frequencies for this normal mode. The Renner-Teller splitting for the DELTA(u 3/2) and the SIGMA(u)- components of nu2+ in the upper 2PI(g 1/2) spin-orbit component has been resolved for the first time. The photoionization efficiency spectra show a strong counter-correlation of the CS2+ and S+ fragments.

引用

页码：542 / 548

页数：7

共 26 条

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