THE CRYSTAL-STRUCTURE OF BIS(2,2'/6',2TERPYRIDINE)NICKEL(II) PERCHLORATE HYDRATE

被引：37

作者：

BAKER, AT

CRAIG, DC

RAE, AD

机构：

[1] UNIV NEW S WALES,SCH CHEM,SYDNEY,NSW 2052,AUSTRALIA

[2] AUSTRALIAN NATL UNIV,RES SCH CHEM,CANBERRA,ACT 0200,AUSTRALIA

来源：

AUSTRALIAN JOURNAL OF CHEMISTRY | 1995年 / 48卷 / 07期

关键词：

D O I：

10.1071/CH9951373

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The crystal structure of bis(2,2':6',2 ''-terpyridine)nickel(II) bis(perchlorate) hydrate has been determined by single-crystal X-ray diffractometry. The compound is monoclinic, space group P2(1), with two molecules in a unit cell of dimensions a 8.827(4), b 8.910(2), c 20.148(9) Angstrom, beta 98.71(2)degrees. The structure was refined by least-squares to a residual of 0.065 for 2184 observed reflections. The compound is found to be isomorphic with the iron(II) analogue previously reported: the cation has approximate D-2d symmetry, with the main distortion from octahedral symmetry being an axial compression. Both the solid state reflectance and solution spectra have been measured and some significant differences are noted.

引用

页码：1373 / 1378

页数：6

共 14 条

[1]

ARRIORTUA MI, 1982, B SOC CHIM BELG, V91, P337

[2] CRYSTAL-STRUCTURE OF BIS(2,2'-6',2''-TERPYRIDINE)IRON(II) BIS(PERCHLORATE) HYDRATE [J].