SOME PENTAFLUOROPHENYL DERIVATIVES OF SILICON

被引：14

作者：

HENGGE, E

STARZ, E

STRUBERT, W

机构：

[1] Institut für Anorganische Chemie der Technischen Hochschule Graz, Graz

来源：

MONATSHEFTE FUR CHEMIE | 1968年 / 99卷 / 05期

关键词：

D O I：

10.1007/BF00904310

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(C6F5)3SiH, formed by the reaction of HSiCl3 and C6F5MgCl, reacts with chlorine to give (C6F5)3SiCl. The latter in a Wurtz reaction yielded the disilan (C6F5)3SiSi(C6F5)3. The electron-withdrawing effect of the C6F5-group on the silicon atom and the weakening of the Si-Si-bond is demonstrated by the Si-H valence vibration and the chemical properties of the disilane. © 1968 Springer-Verlag.

引用

页码：1787 / &

共 12 条

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