GROUP DIPOLE MOMENTS OF METAL-BETA-KETOENOLATE RINGS IN THALLIUM INDIUM AND TIN COMPLEXES

被引：28

作者：

MOORE, CZ

NELSON, WH

机构：

[1] Pastors Chemical Laboratories, University of Rhode Island, Rhode Island 02881, Kingston

来源：

INORGANIC CHEMISTRY | 1969年 / 8卷 / 01期

关键词：

D O I：

10.1021/ic50071a033

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Dipole moments of selected thallium, indium, and tin acetylacetonates, dibenzoylmethanates, and hexafluoroacetylacetonates have been measured in benzene solution at 25° using a refractivity method. The metal-acetylacetonate and metal-dibenzoylmethanate group moments have been found to be less than 2 D. Metal-hexafluoroacetylacetonate group moments have been observed to differ from acetylacetonate moments by about 3 D, as expected. All group moment values obtained are much smaller than those predicted in the literature. © 1969, American Chemical Society. All rights reserved.

引用

页码：143 / &

共 24 条

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